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Why ABS and V0 flame retardants are easy to carbonization?
2018 / 11 / 03
Flame-retardant ABS is made from YISHION ABS resin, with high thermal stability, flame retardants and so on. The preparation methods of flame retardant ABS are usually divided into two types. One is copolymerization of monomers containing halogen elements in graft polymerization, and then the flame retardant ABS is prepared. This method is difficult to achieve satisfactory flame retardancy because of the limitation of the amount of fourth monomers during copolymerization. The two is to blend the compounds or polymers containing halogen elements and other flame retardant additives and ABS resin to make blends of flame retardant ABS, which has been widely used in industrial production. The flame retardant is easily decomposed, carbonized or yellowing at high temperature, so the forming temperature should be as low as possible. It is usually set below 190 C (the resin melt temperature is below 220 C). "Carbonization" is not bad, the flame retardancy principle can be divided into four mechanisms: (1) isolation of oxygen and promoting polymer carbonization to reduce flammable gas production and flame retardancy; (2) produce non flammable gases to dilute oxygen concentration to
Characteristics and application cases of solid calcium-zinc composite heat stabilizer
2018 / 11 / 02
1. Hot spot of solid calcium-zinc composite heat stabilizerEnvironmental protection (relative to lead, cadmium, tin, antimony).Odorless or low-odor (relative to organotin and liquid calcium-zinc), the odor of organotin is derived from mercaptan, liquid calcium-zinc, antimony-zinc stabilizer may be derived from short-chain acid and low-boiling solvent, solid calcium-zinc does not exist these questions.Solid assisted stabilizer technology has developed rapidly (relative to liquid calcium and zinc), especially the use of auxiliary stabilizers represented by hydrotalcites and polyol esters, which has solved the problem of zinc burning.Calcium-zinc stabilizers have made great progress in performance and cost, especially in the hard field. As the formula continues to improve, the cost is decreasing, the performance is improving, and the price has gradually approached the lead salt.2. Formulation system of solid calcium and zincAccording to the principle of primary stabilizer and secondary stabilizer, zinc soap in the calcium-zinc composite heat stabilizer is used as the main stabilizer, while calcium soap is used as the secondary stabilizer. In fact, as the secondary stabilizer, hydrotalcite, zeolite, Polyol (ester), antioxidants, and the like. Therefore, the calcium-zinc composite heat stabilizer should be strictly referred to as [organic zinc composite heat stabilizer", and the common formulation system of solid organic zinc composite heat stabilizer (without hydrazine) has the following structures:---Zinc soap + calcium soap + other;---Zinc soap + hydrotalcite + other;---zinc soap + zeolite + other;---Zinc soap + polyol (ester) + other;---Zinc soap + antioxidant + other;3. Application classification of powdered calcium and zincAccording to heat resistance grade: soft / hardAccording to the influence
2018 / 10 / 29
The global market size of PVC stabilizer, in terms of volume, was 1,088.3 KT in 2014, and is projected to register a CAGR of 4.7% between 2015 and 2020. Asia Pacific: The largest market for PVC Stabilizers Asia-Pacific is the largest market for PVC stabilizers, registering a significant share of 57.1% of the total market in 2014. China is a leading country in Asia-Pacific as well as globally, in terms of volume and value. The market patterns of PVC stabilizer types used for various applications are continuously witnessing an upward trend, mainly due to the increase in the use of PVC in various applications such as pipes & fittings, rigid & semi-rigid films, window profiles, coatings & flooring, and other applications that include medical and consumer goods. The global PVC stabilizers market offers high growth potential in the next five years. Presently, the demand for PVC stabilizers is driven due to dynamic growth in building and construction industry in Asia-Pacific, wide application of PVC, and replacement of conventional materials by PVC in various applications. [Lead stabilizers, the biggest market and organic stabilizers, the fastest-growing markets among various types of stabilizers used for various applications."
Global Epoxidized Soybean Oil Market Trends & Opportunities
2018 / 10 / 27
Among the key end-use segments, the market is gaining maximum from the rising use of epoxidized soybean oil in food and beverages packaging. As the retail sector gears for spike in the demand for processed food, the significance of phthalate-free plasticizers food packaging will scale higher. This will create significant opportunities for the market in the beverage can coating segment as well. JIAAO epoxidized soybean oil is available at a lower cost and offers high flexibility and thermal stability. It is also an eco-friendly bio-plasticizer hence, considered to be a food-grade product. It is due to the same reason that epoxidized soybean oil is extensively used in the food and beverages industry for packaging of products. By application, plasticizers will emerge as one of the key market segments. The segment includes PVA, PVC, and chlorinated rubber applications. The demand for epoxidized soyabean oil is thus considerably high in North America, wherein stringent environmental laws have compelled industries to lower dependence on phthalate plasticizers. Also, soybean oil is most likely to remain the leading segment among raw materials due to its extensive use in the production of epoxidized soybean oil. This vegetable oil is derived from the seeds of soybean and is known to have many inedible applications besides its use in food products. Out of the many inedible appl
Types and Advantages of Organophosphorus Flame Retardants
2018 / 10 / 27
American legislation had updated the flame retardants in furniture and children`s products. The proposal prohibits or restricts the use of halogen flame retardants in children`s products or upholstered furniture. Flame retardant is a basic requirement for the process of plastic production and use. Halogen flame retardant is the most widely used in many plastic flame retardants. But the shortcomings of halogen flame retardants and increasingly strict environmental regulations make the halogen flame retardant face more and more limitations. The market needs a more efficient and environmentally friendly flame retardant. Organophosphorus flame retardants are the same as halogen flame retardant. It has many varieties and is widely used. The halogen flame retardant has many disadvantages, such as the poor anti-UV stability, the burning of more smoke, corrosive gases and toxic gases. Organic phosphorus flame retardants is a hotspot in the study of flame retardant, because of organophosphorus flame retardants also has the plasticizing, thermal stability, etc. It is very significant to improve the comprehensive performance of the molecular material. Types of Organophosphorus Flame Retardants. 1. Phosphate Ester Flame Retardants Phosphate ester flame retardant is the main flame retardant of organophosph
Do flame retardants actually stop the spread of fires?
2018 / 10 / 20
To answer that question, let`s use flame retardant furniture as an example. The number of upholstered furniture fires in the home environment dropped by 84 percent from 1980, the first year that data were available, to 2009, according to NFPA. While several factors have contributed to that sharp decline, the timeframe coincides with the use of flame retardants to meet flammability standards imposed in California in 1976. In the absence of a national requirement, the California standards were broadly followed by the US furniture industry over the following 20 years. Similar findings have been reported in the United Kingdom where flammability standards also are in place for furniture. Despite this substantial progress, upholstered furniture remains a significant contributor to home fire deaths, according to NFPA. During the period from 2005 to 2009, while upholstered furniture was the item first ignited in 2 percent of reported home fires, these fires resulted in 19 percent of the home fire deaths.
2018 / 10 / 19
We Novista are one of the largest manufactures of CPVC and PVC addditives in China with the latest technology and superior R&D team. Which has the manufacturing capacity to meet your polymer material needs with competitively price and qualified solutionsPolyvinyl chloride (PVC) is a versatile and resource efficient thermoplastic with the widest range of applications of any of the plastics family making it useful in virtually all areas of human activity.Without additives PVC would not be a particularly useful substance, but its compatibility with a wide range of additives – to soften it, colour it, make it more processable or longer lasting, results in a broad range of potential applications from car underbody seals and flexible roof membranes to pipes and window profiles. PVC products can be rigid or flexible, opaque or transparent, coloured and insulating or conducting. There is not just one PVC but a whole family of products tailor-made to suit the needs of each application. Unlike most other thermoplastics, the majority of PVC applications have a lifetime of between 10 and 100 years. This requires proven durability and stabilisers play an important part in achieving such performance. All polymers require stabilisers of one sort or another; PVC is no different in this respect.Formulating PVC ProductsBefore PVC can be made into products, it has to be combined with a range of special additives. The essential additives for all PVC materials are stabilisers and lubricants; in the case of flexible PVC, plasticisers are also incorporated. Other additives which may be used include fillers, processing aids, impact modifiers and pigments. Additives will influence or determine the mechanical properties, light and thermal stability, colour, clarity and electrical properties of the product. Once the additives have been selected, they are mixed with the polymer in a process called compounding. One method uses an in
Heat stabilizer market ready for product changes
2018 / 10 / 13
PVC (polyvinylchloride) is a versatile polymer, either rigid or plasticized to yield a flexible plastic. It requires, however, a heat stabilizer. PVC is employed in many applications ranging from flooring, cable, and film made from plasticized vinyl to pipe, profiles, and sheets processed from rigid PVC. However, PVC can only be processed in the presence of heat-stabilizing additives to avoid changes in the chemical structure caused by elevated temperatures and mechanical stresses. Over the last decades lead (Pb) stabilizers were used to stabilize most rigid PVC worldwide except in North America, where tin (Sn) stabilizers dominated. Both systems show similar price/performance ratios; technically, they are incompatible with each other, cannot be recycled together, and thus are used exclusively in selective markets. Now a trend toward stabilizers based on calcium (Ca) and zinc (Zn) as well as organic compounds is emerging. Use of these additives is mainly driven by voluntary commitments, such as the Vinyl 2010 initiative by the European PVC industry, started by key PVC industry players in 2000. It is a 15-year-program to meet the challenges of sustainable development and continuous environmental improvement throughout the European PVC sector. Stabilizer systems based on calcium/zinc (CaZn) deliver some advantages over lead and tin stabilizers. They combine easy handling with good final product properties and excellent outdoor weathering performance. Like lead stabilizers, the are mostly offered as customized one packs. On the other hand, they are more product-specific, often requiring custom formulation for individual applications, when compared to lead-based stabilizer systems. The cost of CaZn stabilizers is now similar to lead stabilizers. To get the complete picture, prices should be compared based on a similar unit length of final product. At first glance
flame retardant uses and benefits
2018 / 10 / 13
When added to different materials, flame retardants can help prevent fires from starting or limit their spread. According to the National Fire Protection Association (NFPA), in 2012, more than 1.3 million fires were reported in the United States, causing 2,855 civilian fire deaths, 16,500 civilian injuries and $12.4 billion in property damage. The use of flame retardants is especially important today, as the large volume of electrical and electronic equipment in today`s buildings, coupled with a larger volume of combustible materials, can increase the potential for fire hazards. Flame retardants provide consumers with a critical layer of fire protection and are vital to reducing the risks associated with fire. Today, flame retardants are used in four major areas: Electronics and Electrical Devices Flame retardants can enable modern electronic equipment, like television, and computers, to meet fire safety standards and are vital to the safety of hundreds of these products. B
3 Surprising Benefits of Using Flame Retardant at your House
2018 / 09 / 29
Flame retardants are products in a home that contain chemicals to decrease or eliminate their flammability, and they work in three different ways to inhibit or minimize the severity of a fire. A flame retardant will decrease the presence of oxygen as well as gasses located close to items that are burning. It will inhibit a material`s ability to ignite. Flame retardants also provide a layer of fire resistant material on a product. 1. Fire Prevention Flame retardants are able to provide a number of consumers products with an essential layer of fire protection. According to FireTect, flame retardants are able to stop fires from starting as well as limit their spread and decrease the amount of damage resulting from a fire. Some are designed to work on their own and others act as a synergist. This means they can increase the fire protective abilities of other types of flame retardants. Product manufacturers use a variety of flame retardants. The materials are very different in their chemical composition and physical nature. Various flame retardants react in different ways with fire. This is why so much care is taken to carefully match a flame retardant to the correct material. They all interact at various stages of a fire`s cycle. A home today contains a number electronic devices such as computers, televisions, microwaves and more. This has resulted in high amounts of composite and plastic materials available in a home. It has significantly increased the fire hazard potential. Flame retardants are becoming increasingly essential to minimize fire damage. They have been able to provide sufficien
what is Methyl Tin Stabilizers
2018 / 09 / 28
Methyl Tin Stabilizers are the new industry standard for providing heat stability in PVC applications. Its effecient heat stabilizing property is used for processing of PVC plastics` in applications such as extruding, molding, coating, injection and calendaring. Methyl Tin Stabilizers provides excellent retention of the initial color along with superior and dynamic heat stability, transparency and weather proofing. Methyl Tin Stabilizers is considered as the most effective stabilizer because of its high performance and environment-friendly feature. Methyl Tin Sabilizers reduces carbonization in a remarkable way.These features of Methyl Tin Stabilizers have enabled it to replace other high-toxic PVC stabilizers in day-to-day applications. Methyl Tin Stabilizers are approved by FDA as well as BGA including other regulatory agencies, this means that they can be used in applications that have direct food contact. Applications: PVC/CPVC Pipes and Fittings, PVC Film, Hose Pipes, Soft Tubes, Compound. For more details, welcome to contact: mandyzhang@novistagroup.com
5 Major Categories of Flame Retardants
2018 / 09 / 15
From mattresses to televisions, children`s toys to carpet padding, we are surrounded by products that contain flame retardants. These chemicals are added to materials or products to prevent or slow the spread of fire. They are broken down into the following 5 major categories: 1. Halogen: Within this class of flame retardants includes chlorine-based systems but perhaps the most well-known are Bromine Flame Retardants (BRFs). BFRs are commonly used by those within the electronics industry and also within textiles, construction products, and coatings. Bromine is used because it releases active bromine atoms into the gas phase before the material reaches its ignition temperature, which quenches the chemical reactions occurring within the flame. This can prevent the burning process from occurring or can slow it such that other measures can be taken to extinguish the fire. This is an example of the vapor phase inhibition approach. One major issue with this type of flame retardant is they are becoming increasingly banned within products due to safety concerns. The RoHS directive, for example, specifically limits the amount of polybrominated biphenyls and polybrominated diphenyl ethers that can be found within appliances, IT equipment, lighting equipment, medical devices, toys, and semiconductors, amongst other product categories.
The importance of environmental awareness in PVC products
2018 / 09 / 14
From the beginning of twentieth Century 80 years, countries around the world have proposed to prohibit the use of lead salt stabilizer, cadmium salts requirements: A, Europe a ,European Standardization Committee approved EN71-3 standard in March 11, 2000, restrictions on soluble eight heavy metals, including lead limit was 90mg/kg; b ,The European Parliament and in 2000 passed the environmental bill 76/769/EEC-PVC material requirements of environmental protection green book, starting from August 2003, in electrical materials banned the use of lead salt and other 18 kinds of harmful substances, in 2015 to prohibit the use of lead salt stabilizer; c ,The European Union in January 27, 2003 promulgated the "restrictions on the use of certain hazardous substances in electrical and electronic equipment" (RoHS), clearly defined,From July 1, 2006 onwards, all in the EU market of large, small household appliances, IT and remote equipment, communications equipment, audio visual equipment, lighting equipment, electrical and electrical tools, toys and leisure and sports equipment, vending machines, eight kinds of electromechanical products shall not contain lead, mercury, cadmium, hexavalent chromium, PBB six, PBDE six, etc. hazardous substances; d ,In 2005 July 6, the European Parliament and the Board issued "on the development of energy consuming product design requirements for environmental protection framework directive 2005/32/EC" (EuP), which in order to improve the overall environmental performance of products, to ensure the security of energy supply, the directive covers all can use products. The production of China's plastics industry impact will be compared to RoHS and REACH regulations more serious; e ,In 2006 22 months 28 days of the European Parliament and the Council of the European Union and put forward "on chemicals registration, evaluation, authorization and restriction sy
What is Calcium-Zinc stabilizer (Ca/Zn stabilizer) ?
2018 / 09 / 11
Calcium/Zinc stabilizers are generally classified into solid and liquid calcium zinc stabilizers. The Calcium-Zinc stabilizer is synthesized by a special compounding process mainly composed of a calcium salt, a zinc salt, a lubricant, an antioxidant, and the like. It can not only replace toxic stabilizers such as lead and cadmium salts and organotins, but also has good thermal stability, light stability and transparency and tinting strength. Practice has proved that in the PVC resin products, the Ca/Zn stabilizer has good processing performance, and the heat stabilization effect is equivalent to the lead salt stabilizer, and is a good non-toxic stabilizer. Solid product The appearance of the calcium-zinc stabilizer is mainly white powder, flake, and paste. Powdered calcium-zinc stabilizer is used as the most widely used non-toxic PVC stabilizer, and is often used in food packaging, medical equipment, wire and cable materials, etc. PVC calcium-zinc stabilizers for rigid pipes have also appeared on the market. The thermal stability of powdered calcium-zinc stabilizer is not as good as that of lead salt stabilizer. It has certain lubricity, poor transparency and easy to blooming. In order to improve the stability and transparency, an antioxidant such as a hindered phenol, a polyhydric alcohol, a phosphite, and a β-diketone is often added to improve. The two major systems of
flame retardant necessity for Polyurethane (PU) Products
2018 / 09 / 08
What are polyurethane products? Polyurethanes refer to a wide range of products that include flexible foams used in furniture and automobiles, rigid foams used as building insulation, durable coatings, adhesives and sealants, and even certain items of apparel. Can
The use of PVC Ca-Zn stabiliser
2018 / 09 / 07
The use of calcium/zinc stabiliser systems has been common in PVC applications for over 25 years. These materials are generally based on metal carboxylates and will sometimes incorporate other elements to boost performance such as aluminium or magnesium. Because the heat stability in some applications may require some enhancement when using calcium/zinc, organic co-stabilisers will also often be added to this type of formulation. These materials include polyols, epoxydised soya bean oil, antioxidants and organic phosphites. Properties and Applications Because of the characteristics of calcium/zinc stabilised materials they are widely used in many flexible and rigid PVC applications. This type of stabilising system can give products which have a high degree of clarity, good mechanical and electrical properties, excellent organoleptic properties and good outdoor weatherability. As a result, calcium/zinc stabilisers have been incorporated and established in a wide range of applications as shown in table two. These include toys, healthcare products, such as blood bags, semi-rigid and flexible foil for food packaging, bottles for potable water, as well as for potable water pipe. The performance
MMA market analysis (30/08/2018)
2018 / 08 / 31
(MMA Factories operatin rate) The current shortage of Methyl Methacrylate (MMA) may get worse. A new study by IHS Markit (London) shows that the demand for this chemical has been increasing in the production of plastics, paints, coatings and adhesives, and that this chemical is due to operational problems in production and production facilities. The supply is limited. IHS Markit Global Acrylate and Superabsorbent Polymer (SAP) Market Consulting Services Company expects global demand for MMA to reach 3.7 million tons by 2018. By 2023, demand is expected to exceed 4.3 million tons, which is largely driven by growing demand for coatings and adhesives in China and elsewhere. In the next five years, the average increase in global demand will be slightly higher than 3%, while the more mature market will increase by 2% during this period. Their report shows that in the past 18 months, China's MMA prices have been rising steadily. In Western Europe and the United States, producers also benefit from higher prices during the same period. Since January 2017, European prices have risen by nearly 60%. In the same period, US house prices rose by nearly 20%. Denis Poussin, Head of global acrylate research at IHS Markit and lead author
What byproducts are found in smoke?
2018 / 08 / 25
The combustion of products that contain organic materials produce carbon monoxide, carbon dioxide, and water. So, for example, burning common materials like wood will produce these substances. Products that contain nitrogen will also produce certain amounts of hydrogen cyanide and nitrogen oxides. Common products that contain nitrogen include sheep`s wool, silk, and composite wood products using polyurethane binders. Smoke and byproducts from fires are toxic regardless of the source of those fires and what is being burned.
2018 / 08 / 21
Chlorinated polyethylene (CPE) is made from high density polyethylene (HDPE) polymers prepared by chlorination reaction. According to the different structures and usages, Chlorinated polyethylene resin can be divided into two categories: Chlorinated polyethylene (CPE) and Elastomer CPE (CM) . Resin CPE product is also known as type-A material and elastomer CPE rubber type-B material. Mainly used in wire and cable (mining cables, UL and VDE standards set forth in the wire), hydraulic hoses, automotive hoses, duct tape, plastic sheet, PVC profile pipe modification, magnetic materials, modification of ABS and so on. Rubber Type CPE In the late 1990 of 20th century, the growing domestic demand for high performance flame retardant rubber, especially the development of the wire and cable industry, auto parts manufacturing, have led the consumer demand for rubber-CPE. Rubber-CPE is a good comprehensive performance, heat aging oxygen-ozone, excellent flame retardant special synthetic rubber. Modification Type CPE Chlorinated polyethylene (CPE) is part of the polyethylene chain of hydrogen atoms replaced by chlorine atoms. Mass percentage of chlorine is generally 25%~45%.
2018 / 08 / 18
Measures which prolong escape time, such as introducing fire safe furniture, ensure that fewer people are killed or injured in fires. Flame retardants are an effective element to protect people from fires. They can significantly delay ignition in the early stages of a fire when it can still be extinguished, or occupants of a building can escape. Flame retardants can act in three different ways to stop the burning process and create such a delay. They may work to: 1. Disrupt the combustion stage of a fire cycle including avoiding or delaying [flashover," or the burst of flames that engulfs a room and makes it much more difficult to escape. 2. Limit the process of decomposition by physically insulating the available fuel sources from the material source with a fire-resisting [char" lay 3.
2018 / 08 / 14
AC Blowing Agent AC blowing agent or azodicarbonamide is a chemical compound with the molecular formula C2H4O2N4. It is a yellow to orange red, odorless, crystalline powder,specific gravity of 1.66, nontoxic, stink-free, flammable, capable to generate tremendous froth. During decomposition, 32% weight decomposed into gas, 27% sublimed, 41% residues. Decomposition heat: 359.5 J/g; specific heat: 0.26; combustion heat: 1070 KJ/mol. Appearance:Yellow to orange red, odorless, crystalline powder Molecular formula: C2H4N4O2 Molecular weight: 116.08 CAS No.: 123-77-3 HS No.: 2927.0000.90 Function : capable to generate tremendous froth,Used in producing inflating agent of foam. Application : Suitable PVC,EVA,PP,PE,PS foaming products,especially suitable for WPC ,PVC foamed products.  
SCO will be held in China in June of 2018
2018 / 03 / 28
East China's Qingdao City will host the Shanghai Cooperation Organization Summit in June this year, the provincial governor of Shandong said Thursday. "Shandong will take the opportunity to promote its international reputation," said Gong Zheng when delivering the government work report at the local parliamentary session. Shandong is the birthplace of many ancient Chinese thinkers, including Confucius. In 2017, its GDP exceeded 7.2 trillion yuan (about 1.1 trillion U.S.dollars). The summit has China, Russia, Kazakhstan, Kyrgyzstan, Tajikistan, Uzbekistan, India and Pakistan as full members. Novista-Reprint the News. Beijing: India for the first time took part in a meeting of the international military cooperation departments of the Shanghai Cooperation Organisation (SCO) since joining the bloc
Brief introduction of Methyl Tin stabilizer
2018 / 03 / 06
Methyl tin stabilizer is an efficient stabilizer used in PVC hot working process. Its stability, transparency, compatibility and weather resistance are all superior to other organotin heat stabilizers. It is widely used in PVC sheet, panel, tubing and blow molding and injection molding products. It can also be used in food packaging, medicine packaging and non-toxic and harmless PVC products. Overseas, PVC products of various foods, medicine packaging and storage, and container and tubing for supplying drinking water with high requirements have all employed methyl tin as stabilizer. Its products boast pure color and luster, less odor vanishing fast and reliable safety performance. With the same effect, the using amount of methyl tin is reduced by 15-20% than that of other similar organotin stabilizers. Our company`s products have passed the ROHS certification.
Что входит в состав оконного профиля помимо ПВХ?
2018 / 02 / 28
Основным сырьем для изготовления оконного профиля служит поливинилхлорид. Кроме этого, в его состав входят различные добавки для придания пластику необходимых свойств. Именно благодаря специальным модификаторам, стабилизаторам, антиоксидантам и другим группам веществ пластик получает характеристики долговечности, прочности, сохранности формы и цвета. Все производители профиля является обладателями собственной уникальной рецептуры, которая является производственным секретом и строго охраняется. Однако, есть определенные соотношения, которых более или менее придерживаются все производители. Часто с целью снижения себестоимости производитель увеличивает массовую долю наполнителя в составе профиля - гидрофобного мела. Это самый дешевая составляющая и если его добавить достаточно много, то себестоимость станет закономерно ниже. Однако, чем больше в составе мела, тем более хрупким и менее долговечным станет профиль.
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Email:manager.han@novistagroup.com
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